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I'm sorry for misinterpreting your intention.

And no, I was not just thinking of ionic solids. For instance take ice. A molecule of H2O has no net charge, but locally there is a pattern of positive and negative charges on the surface which results in a predictable crystal structure. Most molecules aren't that strongly polarized, but no matter what there is always some pattern of charges, and atoms will tend to line up so that positive meets negative and they attract. They will do this even when passing by quickly, hence the Van der Waals forces.



You are right about ice, but metals (which are comprised of neutral atoms which lack an intrinsic dipole moment like that of H2O, and nearly always have crystalline structure) are not held together by Van der Waals or similar forces - one needs to invoke quantum mechanics to get even a qualitative picture of why they stick together.

Consider for instance Sodium. If there were no force other than Van der Waals holding the atoms together in the crystal, there is no explanation for the fact that Argon, a significantly heavier atom, has much lower melting and boiling points.




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