I'm fond of "A Fire Upon the Deep" by Vernor Vinge, and its kind of prequel "A Deepness in the Sky", they both contain some great ideas and I love the fact they have some very alien aliens!
Oh and if you haven't read any Douglas Adams "The Hitchhiker's Guide to the Galaxy" is fantastic
Seconding "A Fire Upon the Deep": a fast-paced, high-stakes action adventure in a zany, 5th Element-esque space opera universe. Explores the idea of strong AI in a unique and interesting way.
Love both of these. Perhaps more so "A Deepness in the Sky", with its darker tone, very thoughtful programming-related remarks, and the reversed "alien invasion" concept.
His books are great, I loved both "fire upon deep" and a "deepness in the sky". It is unfortunate he inspired the Singularity movement which I find full of bullshit and religious overtones.
Oh and if you haven't read any Douglas Adams "The Hitchhiker's Guide to the Galaxy" is fantastic