The difference between populism and democracy is that populists always claim to speak "for the people" even if the people are divided. They'll even take action against the majority and simply claim that all the "real" people are for it.
Then secede? Have a majority referendum in your respective states about it and tell us how it goes. Either that or admit that part of being part of the union is agreeing with the electoral college and the outcomes that arise from it.
As much as I think that the majority Democrat States should suck it up about losing the election, I also think it's fully within their rights to secede if their populace wishes.